The formula
Subscript 1 is the gas before a change, and subscript 2 is after. is pressure, volume and absolute temperature (kelvin).
Where it comes from
Start from the ideal gas law, , and divide both sides by :
If no gas gets in or out, the amount stays the same, and is a constant. So has the same value before and after any change. Setting the two states equal gives the combined gas law.
It also contains the three older gas laws as special cases:
- Boyle’s law (constant ):
- Charles’s law (constant ):
- Gay-Lussac’s law (constant ):
Worked example
2.00 L of gas at 1.00 atm and 25 °C is compressed to 2.50 atm and heated to 100 °C. First convert the temperatures to kelvin, 298.15 K and 373.15 K. Then solve for :
Raising the pressure 2.5 times would shrink it to 0.80 L, but heating pushes it back out to about 1.00 L.
Watch out for
- Kelvin, always. Using °C gives wrong answers, and divides by zero at 0 °C. The calculator converts for you.
- Same units on both sides. Pressures and volumes cancel, so any unit works as long as both states use it. Temperature is the exception and must be absolute.
- Real gases drift from this at high pressure or near condensation.
Sources
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